Answer: If matter goes through a chemical change then the physical properties are not likely to stay the same.
Explanation:
When chemical composition of a substance changes during a chemical reaction then it is called a chemical change.
Chemical change always leads to the formation of new substances. Properties like chemical reactivity, combustion, rusting etc are chemical changes.
For example, [tex]N_{2} + 3H_{2} \rightarrow 2NH_{3}[/tex]
Here, [tex]NH_{3}[/tex] will have different chemical as well as physical properties as compared to [tex]N_{2}[/tex] and [tex]H_{2}[/tex].
As physical properties are the properties that cause change in state of a substance.
Properties like boiling point, state of substance etc are physical properties.
Thus, we can conclude that if matter goes through a chemical change then the physical properties are not likely to stay the same.
1. Which of the combinations in the lab activity had indications that a chemical change occured? Defend your argument with evidence.
2. Which of the combinations in the lab activity had indications that a physical change occured? Defend your argument with evidence.
3. Are all physical changes reversible? Explain your answer using an example you've observed in your everyday life.
4. Give an example of something you've observed in your everyday life that is a chemical reaction. How did you know it was a chemical reaction?
Answer:The green growing on the penny of copper and the rust forming on the nail of iron are chemical changes. Boiling away salt water, scraping iron filings from a mixture of sand with a magnet, and breaking a rock with a hammer, are physical changes.
Explanation:
Perform the following operation and express the answer in scientific notation.
7.296×10² ÷ 9.6×10^-9
Answer:
7.6×10¹⁰
Explanation:
7.296×10²÷9.6×10⁻⁹
To solve such problem,
We group the whole number ans solved seperately and also group the indices and solve the seperately
Step1 : 7.296/9.6 = 0.76
Step 2: applying the law of indices,
10²÷10⁻⁹ = 10⁽²⁺⁹⁾ = 10¹¹
Therefore,
7.296×10²÷9.6×10⁻⁹ = 0.76×10¹¹ = 7.6×10¹⁰
Which equation expresses the solubility product of Zn3(PO4)2?
a. Ksp = [Zn2+][PO43]
b. Ksp = [Zn2+]3 [PO43]2
c. Ksp = 6[Zn2+][PO43]2
d. Ksp = 108[Zn2+][PO43]2
⇒b. Ksp = [Zn2+]3 [PO43]2
Hope It Helps You ✌️
define saturated and unsaturated fats
Answer:
unsaturated fats, which are liquid at room temperature,are different from saturated fat because they contain one or more double bonds and fewer hydrogen atoms on their carbon chain.
Be sure to answer all parts.
Calculate the molarity of each of the following solutions:
(a) 28.5 g of ethanol (C2H5OH) in 4.50 x 102 mL of solution
M M
es
(b) 21.6 g of sucrose (C12H22011) in 67.0 mL of solution
M
(c) 6.65 g of sodium chloride (NaCl) in 96.2 mL of solution
M
Answer: The molarity of each of the given solutions is:
(a) 1.38 M
(b) 0.94 M
(c) 1.182 M
Explanation:
Molarity is the number of moles of a substance present in liter of a solution.
And, moles is the mass of a substance divided by its molar mass.
(a) Moles of ethanol (molar mass = 46 g/mol) is as follows.
[tex]Moles = \frac{mass}{molar mass}\\= \frac{28.5 g}{46 g/mol}\\= 0.619 mol[/tex]
Now, molarity of ethanol solution is as follows.
[tex]Molarity = \frac{moles}{Volume (in L)}\\= \frac{0.619 mol}{4.50 \times 10^{2} \times 10^{-3}L}\\= 1.38 M[/tex]
(b) Moles of sucrose (molar mass = 342.3 g/mol) is as follows.
[tex]Moles = \frac{mass}{molar mass}\\= \frac{21.6 g}{342.3 g/mol}\\= 0.063 mol[/tex]
Now, molarity of sucrose solution is as follows.
[tex]Molarity = \frac{moles}{Volume (in L)}\\= \frac{0.063 mol}{0.067 L} (1 mL = 0.001 L)\\= 0.94 M[/tex]
(c) Moles of sodium chloride (molar mass = 58.44 g/mol) are as follows.
[tex]Moles = \frac{mass}{molar mass}\\= \frac{6.65 g}{58.44 g/mol}\\= 0.114 mol[/tex]
Now, molarity of sodium chloride solution is as follows.
[tex]Molarity = \frac{moles}{Volume (in L)}\\= \frac{0.114 mol}{0.0962 L}\\= 1.182 M[/tex]
Thus, we can conclude that the molarity of each of the given solutions is:
(a) 1.38 M
(b) 0.94 M
(c) 1.182 M
A student dropped a piece of nickel metal into a solution of HCl(aq). He observed the formation of gas bubbles and collected the gas into another test tube. The student performed a splint test and observed that the splint flared up when he placed the splint into the test tube of the gas. What can be said about the results of this students experiment?
a. The student performed the splint test incorrectly. He should of observed a popping sound when the splint was placed in the test tube.
b. The experiment was performed incorrectly. Nickel doesn't react with HCl. Therefore, the student picked up the wrong metal when conducting the experiment.
c. The student completed the experiment correctly and there were no errors in the experiment.
d. The student performed the splint test incorrectly. He should of observed the flame being extinguished when the splint was placed in the test tube.
Answer:
a. The student performed the splint test incorrectly. He should of observed a popping sound when the splint was placed in the test tube.
Explanation:
It is given that a student performed an experiment where he dropped a nickel metal in to HCl solution. He observed the reaction and performed a splint test in the test tube that is filled with a gas which is formed while Nickle is dropped into the solution of HCl.
But the experiment that the student performed was incorrect. He must have observed the popping sound when the splint was placed in the test tube.
When the splint was added to the gas splint flared up. The hydrogen gas pops out when exposed to the flame.
[tex]$Ni + HCl(aq) = NiCl + H_2$[/tex]
Thus the correct option is (a).
Ammonia is produced by the reaction of nitrogen and hydrogen: N2(g) + H2(g) NH3(g)
(a) Balance the chemical equation.
(b) Calculate the mass of ammonia produced when 35.0g of nitrogen reacts with hydrogen.
Answer:
a) N2 (g) + H2 = 2 NH3
b) You have to state the mass of hydrogen
(S)-Pentan-2-ol was treated sequentially with methanesulfonyl chloride (CH3SO2Cl) and then potassium iodide. What is the final product that forms
Answer:
(S)-Pentan-2-ol was treated sequentially with methanesulfonyl chloride (CH3SO2Cl) and then potassium iodide. What is the final product that forms
Explanation:
Alcohols are poor leaving groups.
To make -OH group a better-leaving group, it should be treated with sulfonyl chlorides.
Then, methane sulfonyl group makes will be substituted on the -OH group and forms sulfonyl esters and makes it a better leaving group.
After that treating with KI proceeds through nucleophilic bimolecular substitution and the final product formed is shown below:.
7.23 One equivalent of sodium methanethiolate is added to an electrophile that has two leaving groups. Which product will be major
The question is incomplete, the complete question is shown in the image attached to this answer
Answer:
A
Explanation:
We can see from the conditions of the reaction that the incoming nucleophile is -SCH3 and there are two possible leaving groups in the substrate.
First of all, we have to look at the conditions of the reaction. We can see that the reaction is taking place in DMF, a polar aprotoc solvent. This condition favours the SN2 synchronous mechanism over the SN1 ionic mechanism.
Hence, the nucleophile at the 1-position is preferentially substituted owing to the conditions of the reaction.
Thus, option A is the major product of the reaction.
calculate the molarity in a 0.550 m solution of NaCl in water. Assume that the solution density is 1.03g/mol
Answer:
M=0.549M
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us to perform this calculation by firstly assuming we have 1 kg of water as the solvent so that we have 0.550 moles of NaCl as well. Moreover, we realize we have 1000 grams of water and the correct mass of the solution can be calculated by converting 0.550 moles of NaCl to grams by using its molar mass:
[tex]m_{solute}=0.550mol*\frac{58.44 g}{1mol}= 32.14g\\\\m_{solution}=1000g+32.14g=1032.14g[/tex]
And subsequently, the volume in liters by using the density and the correct conversion factor:
[tex]V_{solution}=1032.14g*\frac{1mL}{1.03g} *\frac{1L}{1000mL} =1.002L[/tex]
Finally, the molarity will be:
[tex]M=\frac{0.550mol}{1.002L} =0.549M[/tex]
Regards!
What should be done if a spectrophotometer reports an absorbance that is too high? Select one: Reposition the cuvette in the spectrophotometer. Pour out half the volume of the sample. Restart the spectrophotometer and try again. Dilute the sample. g
Answer:
The sample should be diluted
Explanation:
According to Beer Lambert's law, the absorbance of a sample depends on the concentration of the sample.
Hence, if the concentration of the sample is very high, the spectrophotometer will also report a very high value of absorbance.
When this is the case, the sample should simply be diluted and the readings are taken again using the spectrophotometer.
What quantity of heat is transferred when a 150.0g block of iron metal is heated from 25.0°C to 73.3°C? What is the direction of the heat flow?
The direction of heat flow is increased which means blocks temperature is higher and hotter than it was before
Organic foods do not contain chemicals.
True
Or
False
Answer:
True
Explanation:
The word Organic refers to the methods used to cultivate and process farm agricultural products. Organic foods are edible and nutritious substances consumed (both plants and animals) that are free from the use of synthetics and chemicals. In plants, the include the use of organic manure that serves as fertilizers and carrying out the weeding process by hand weeding. In animals, diseases can be prevented by maintaining a clean house or rotational grazing.
The benefit of organic foods are to produce food substances with no chemical substances.
Why the catalytic and optical properties of nanomaterial are different from bulk material
Answer:
The material properties of nanostructures are different from the bulk due to the high surface area over volume ratio and possible appearance of quantum effects at the nanoscale. ... Yu; they found that the structural distortions on the quantum dots depend both on the kind of dopant and on the size of the dots.
Explanation:
hope it helps
Na2CO3 reacts with dil.HCl to produce NaCl, H2O and CO2. If 21.2 g of pure Na2CO3 are added in a solution containing 21.9g HCl , a. Find the limiting reagent. (2) b. Calculate the number of moles of excess reagent left over.(2) c. Calculate the number of molecules of H2O formed.(1) d. Calculate volume of CO2 gas produced at 270C and 760mm Hg pressure.(2) e. Write significance of limiting reagent
Answer:
See explanation
Explanation:
Equation of the reaction;
Na2CO3(aq) + 2HCl(aq) -------> 2NaCl(aq) + H2O(l) + CO2(g)
Number of moles of Na2CO3 = 21.2g/106g/mol = 0.2 moles Na2CO3
Number of moles of HCl = 21.9g/36.5g/mol = 0.6 moles of HCl
1 mole of Na2CO3 reacts with 2 moles of HCl
0.2 moles of Na2CO3 reacts with 0.2 × 2/1 = 0.4 moles of HCl
Hence Na2CO3 is the limiting reactant
Since there is 0.6 moles of HCl present, the number of moles of excess reagent=
0.6 moles - 0.4 moles = 0.2 moles of HCl
1 mole of Na2CO3 forms 1 mole of water
0.2 moles of Na2CO3 forms 0.2 moles of water
Number of molecules of water formed = 0.2 moles × 6.02 × 10^23 = 1.2 × 10^23 molecules of water
1 mole of Na2CO3 yields 1 mole of CO2
0.2 moles of Na2CO3 yields 0.2 moles of CO2
1 mole of CO2 occupies 22.4 L
0.2 moles of CO2 occupies 0.2 × 22.4 = 4.48 L at STP
Hence;
V1=4.48 L
T1 = 273 K
P1= 760 mmHg
T2 = 27°C + 273 = 300 K
P2 = 760 mmHg
V2 =
P1V1/T1 = P2V2/T2
P1V1T2 = P2V2T1
V2 = P1V1T2/P2T1
V2 = 760 × 4.48 × 300/760 × 273
V2= 4.9 L
The limiting reactant is the reactant that determines the amount of product formed in a reaction. When the limiting reactant is exhausted, the reaction stops.
Please can someone please help me !!
Answer:
False
Explanation:
Question 4 of 30
Scientific research shows that Earth's climate is changing due to human
activities. How can scientific research on climate change help society?
A. It can help us stop storms before they occur.
B. It can help us find a new way to make more water.
C. It can help us track how quickly elements of the climate are
changing
D. It can help us reverse the effects of climate change.
th
C. It can help us track how quickly element of the climate are changing
1. Calculate the number of moles of aluminum, sulfur, and oxygen atoms in 8.00 moles of aluminum sulfate, Al2(SO4)3. 2. Calculate the number of moles of magnesium, chlorine, and oxygen atoms in 6.10 moles of magnesium perchlorate, (Mg(CIO4)2.3. A sample of propane, C3H8, contains 13.8 moles of carbon atoms. How many total moles of atoms does the sample contain?4. A rare gold coin (24 karat, or 100% gold) has a mass of 25.54 g. How many atoms of gold are present in this coin?
Answer:
1) 16.0 moles Al
24.0 moles S
96.0 moles O
2)In 6.10 moles magnesium perchlorate, (Mg(CIO4)2 we have:
6.10 moles Mg
12.2 moles Cl
48.8 moles O
3)4.6 moles of propane (total) contains 13.8 moles of carbon and 36.8 moles of hydrogen atoms
4)The gold coin contains 7.8 *10^22 atoms
Explanation:
Step 1: Data given
Number of moles of aluminum sulfate, Al2(SO4)3 = 8.00 moles
Step 2: Calculate the number of moles
In 1 mol of aluminum sulfate, Al2(SO4)3 we have:
2 moles of Al
3 moles of S
12 moles of O
This means that in 8.00 moles of aluminum sulfate, Al2(SO4)3 we have:
2*8.00 = 16.0 moles Al
3*8.00 = 24.0 moles S
12*8 = 96.0 moles O
2. Calculate the number of moles of magnesium, chlorine, and oxygen atoms in 6.10 moles of magnesium perchlorate, (Mg(CIO4)2
1 mol of magnesium perchlorate, (Mg(CIO4)2 has:
1 Mol of Mg
2 moles of Cl
8 moles of O
In 6.10 moles magnesium perchlorate, (Mg(CIO4)2 we have:
1 * 6.10 moles = 6.10 moles Mg
2*6.10 = 12.2 moles Cl
8*6.10 = 48.8 moles O
3. A sample of propane, C3H8, contains 13.8 moles of carbon atoms. How many total moles of atoms does the sample contain?
In 1 mol of propane, C3H8 we have:
3 moles of C and 8 moles of H
This means if we have 13.8 moles of carbon, we have 13.8/3 = 4.6 moles of propane, C3H8 and 4.6 *8 = 36.8 moles of H
So 4.6 moles of propane contains 13.8 moles of carbon and 36.8 moles of hydrogen atoms
4. A rare gold coin (24 karat, or 100% gold) has a mass of 25.54 g. How many atoms of gold are present in this coin?
Calculate moles of gold:
Moles = mass of gold / molar mass gold
Moles = 25.54 grams / 196.97 g/mol
Moles = 0.1297 moles
Calculate atoms:
Number of atoms = moles * number of Avogadro
0.1297 * 6.022 *10^23 = 7.8 *10^22 atoms
The gold coin contains 7.8 *10^22 atoms
Calculate the mass of Na2S needed if a solution containing 2g of Hg(NO3)2 was added to Na2S solution.
( Hg= 200.59, N= 14, O= 16, Na= 23, S=32)
Answer:
1.433g of HgS are produced
Explanation:
A Solution Containing 2.0 Grams Of Hg(NO3)2 Was Added To A Solution Containing 2.0 Grams Of Na2S. Calculate the mass of the HgS that was formed (it is a precipitate) according to this reaction:
Based on the reaction:
Na2S + Hg(NO3)2 → HgS + 2NaNO3
To solve this question we need to find the moles of each reactant in order to find the limiting reactant. The moles of limiting reactant = moles of HgS:
Moles Na2S -Molar mass: 78.0452 g/mol-
2.0g * (1mol / 78.0452g) = 0.0256 moles Na2S
Moles Hg(NO3)2 -324.7g/mol-
2.0g * (1mol / 324.7g) = 0.006159 moles Hg(NO3)2
As the reaction is 1:1, and moles of Hg(NO3)2 < moles Na2S
The moles of Hg(NO3)2 = Moles HgS = 0.006159 moles
The mass is:
Mass HgS -Molar mass: 232.66g/mol-:
0.006159 moles * (232.66g/mol) =
1.433g of HgS are produced
define a fluid very sort answer
Answer:
A fluid is a medium that has a defined mass and volume, but no fixed shape, at a constant temperature and pressure. This may include gases, liquids, plasmas, and to some extent plastic solids. A fluid can flow and deform, preventing it from carrying loads in a static equilibrium. A fluid is always compressible and internal frictional forces always occur due to the viscosity of the fluid.
If 0.21J of heat cause a 0.308 degree C temperature change, what mass of water is present?
a 0.0702 g
b 0.00540 g
c 0.163 g
d 18.4 g
Answer:
The correct answer is Option c (0.163 g).
Explanation:
Given:
Heat energy,
Q = 0.21 J
Specific heat,
c = 4.184 J/g°c
Change in temperature,
ΔT = 0.308°C
As we know,
⇒ [tex]Q=mc \Delta T[/tex]
By substituting the values, we get
[tex]0.21=m\times 4.184\times 0.308[/tex]
[tex]m=\frac{0.21}{0.308\times 4.184}[/tex]
[tex]=\frac{0.21}{1.28867}[/tex]
[tex]=0.163 \ g[/tex]
8.7 Two products are formed in the following reaction in a 50:50 mixture. Would the resulting solution be optically active
Answer:
Yes. The solution would be optically active.
Explanation:
Diastereomer are defined as the image that is non mirror and non -identical. It is made up of two stereoisomers. They are formed when the two stereoisomers or more than two stereoisomers of the compound have the same configuration at the equivalent stereocenters.
In the given context, as the product given is a diastereomeric mixture, the product would have an optical activity in total.
So the answer is Yes.
Many home barbeques are fueled with propane gas (C3H8)(C3H8). Part A What mass of carbon dioxide is produced upon the complete combustion of 27.9 LL of propane (the approximate contents of one 5-gallon tank)
Answer:
41264 g of CO₂
Explanation:
Combustion reaction is:
C₃H₈ + 5O₂ → 3CO₂ + 4H₂O
1 mol of propane react to 5 moles of oxygen in order to proudce 3 moles of carbon dioxide and 4 moles of water.
In a combustion reaction, our reactant reacts to oxygen and the products are always CO₂ and water.
We have the volume of propane but we need moles of it, so we need to apply density.
Density = mass / volume so mass = density . volume.
Density of propane is: 493 g/L
Mass of propane is 493 g/L . 27.9L = 13754.7 g
We convert mass to moles: 13754.7 g . 1 mol/ 44g = 312.6 moles
According to reaction, 1 mol of propane can produce 3 moles of CO₂
Our 312.6 moles will produce 312.6 . 3 = 937.8 moles
We convert moles to mass: 937.8 mol . 44 g/mol = 41264 g
I have an unknown volume of gas at a pressure of 0.50 atm and a temperature of 325 K. If I raise the pressure to 1.2 atm, decrease the temperature to 320 K, and measure the final volume to be 48 liters, what was the initial volume of the gas?
SHOW YOUR WORK
Answer:
the answer is 2.1 atm
Explanation:
the way people normally do it is by simply deciding the 325k with the 1.2
1.Using the absorbance of the spinach extract and the equation of the trendline, determine the concentration of the extract solution. Report the concentration in moles/L (M).
2. Calculate the number of rams of chlorophyll-a in the 25ml, spinach solution.
3. Calculate the concentration of the chloropyhll-a soultion in spinach (mg chlorophyll-a/g spinach)
Trendline: y=1609x + .0055
Absorbance spinach extract lamda max: .329
Absorbacne spinach extract, 750 nm: .023
Corrected absorbance: .306
Mass of Spinach: .1876g Total Volume of spinach: 25mL
Answer:
Explanation:
From the given information:
We are to make use of the spinach absorbance extract which is the corrected absorbance (y) = 0.306
And also the trendline equation:
y = 1609x + 0.0055
where,
x = absorbance of the spinach extract.
∴
0.306 = 1609x + 0.0055
collecting the like terms
0.306 - 0.0055 = 1609x
0.3005 = 1609x
x = 0.3005/1609
x = 1.8676 × 10⁻⁴
x ≅ 0.0002 M
No. of grams for the chlorophyll can be computed as follows:
recall that:
molar mass of chlorophyll = 893.5 g/mol
the volume = 25ml = (25/1000) L = 0.025 L
∴
In spinach solution, the no. of grams for the chlorophyll:
= (0.0002) mol/L × (893.5 g/mol) × (0.025) L
= 0.0044675 g
≅ 0.0045 g
In the spinach, the concentration of chlorophyll = no of grams of chlorophyll/ mass of the spinach
= 4.5 mg/0.1876 g
= 23.987 mg/g
≅ 24 mg/g
From the given information:
We are to make use of the spinach absorbance extract which is the corrected absorbance (y) = 0.306ChlorophyllChlorophyll is any member of the class of the green pigments involved in the photosynthesis process.
And also the trendline equation:
y = 1609x + 0.0055
where,
x = absorbance of the spinach extract.
so 0.306 = 1609x + 0.0055
collecting the like terms
0.306 - 0.0055 = 1609x
0.3005 = 1609x
x = 0.3005/1609
x = 1.8676 × 10⁻⁴
x ≅ 0.0002 M
2. No.of grams for the chlorophyll can be computed as follows:
recall that:
molar mass of chlorophyll = 893.5 g/mol
The volume = 25ml = (25/1000) L = 0.025 L
Therefore:
In spinach solution, the no. of grams for the chlorophyll:
= (0.0002) mol/L × (893.5 g/mol) × (0.025) L
= 0.0044675 g
≅ 0.0045 g
3. In the spinach, the concentration of chlorophyll = no of grams of chlorophyll/ mass of the spinach
= 4.5 mg/0.1876 g
= 23.987 mg/g
≅ 24 mg/g
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How much energy is required to melt 2 kg of gold? Use the table below and this equation.
a. 125.6 kJ
b. 1729 kJ
c. 10.4 kJ
d. 3440kJ
The equation for the energy required to melt 2 kg of gold is 3440 kJ.
What is energy?Energy is the ability to do work or cause change. It is an essential part of everyday life and is present in many forms, such as thermal energy, electrical energy, chemical energy, and mechanical energy. Energy can be converted from one form to another in order to do work.
The equation for calculating the energy required to melt a certain mass of material is Q = m x Lf, where Q is the energy required (in joules), m is the mass of the material (in kilograms), and Lf is the latent heat of fusion (in joules per kilogram).
Using the table below, we can see that the latent heat of fusion for gold is 1760 kJ/kg. Therefore, the equation for the energy required to melt 2 kg of gold is: Q = 2 kg x 1760 kJ/kg = 3440 kJ.
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Using the balanced equation for the combustion of ethane: 2C2H6 + 7O2 → 4CO2 + 6H2O, how many moles of O2 needed to produce 12 moles of H2O?
Answer:
14 moles of oxygen needed to produce 12 moles of H2O.
Explanation:
We are given that balance eqaution
[tex]2C_2H_6+7O_2\rightarrow 4CO_2+6H_2O[/tex]
We have to find number of moles of O2 needed to produce 12 moles of H2O.
From given equation
We can see that
6 moles of H2O produced by Oxygen =7 moles
1 mole of H2O produced by Oxygen=[tex]\frac{7}{6}[/tex]moles
12 moles of H2O produced by Oxygen=[tex]\frac{7}{6}\times 12[/tex]moles
12 moles of H2O produced by Oxygen=[tex]7\times 2[/tex]moles
12 moles of H2O produced by Oxygen=14 moles
Hence, 14 moles of oxygen needed to produce 12 moles of H2O.
The amount of oxygen required for the combustion of ethane to produce 12 moles of water is 14 moles.
How are the moles produced in reaction calculated?The moles of oxygen produced in the reaction can be given from the stoichiometric law of the balanced chemical equation.
The balanced chemical equation for the combustion of ethane is:
[tex]\rm 2\;C_2H_6\;+\;7\;O_2\;\rightarrow\;4\;CO_2\;+\;6\;H_2O[/tex]
The 6 moles of water are produced from 7 moles of oxygen. The moles of oxygen required to produce 12 moles of water are:
[tex]\rm 6\;mol\;H_2O=7\;mol\;Oxygen\\12\;mol\;H_2O=\dfrac{7}{6}\;\times\;12\;mol\;O_2\\ 12\;mol\;H_2O=14\;mol\;O_2[/tex]
The moles of oxygen required to produce 12 moles of water are 14 moles.
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Consider the titration of 30 mL of 0.030 M NH3 with 0.025 M HCl. Calculate the pH after the following volumes of titrant have been added: a) 0 mL; b) 10 mL; c) 20 mL; d)35 mL; e) 36 mL; f) 37 mL.
Answer:
a)10.87
b)9.66
c)9.15
d)7.71
e) 5.56
f) 3.43
Explanation:
tep 1: Data given
Volume of 0.030 M NH3 solution = 30 mL = 0.030 L
Molarity of the HCl solution = 0.025 M
Step 2: Adding 0 mL of HCl
The reaction: NH3 + H2O ⇔ NH4+ + OH-
The initial concentration:
[NH3] = 0.030M [NH4+] = 0M [OH-] = OM
The concentration at the equilibrium:
[NH3] = 0.030 - XM
[NH4+] = [OH-] = XM
Kb = ([NH4+][OH-])/[NH3]
1.8*10^-5 = x² / 0.030-x
1.8*10^-5 = x² / 0.030
x = 7.35 * 10^-4 = [OH-]
pOH = -log [7.35 * 10^-4]
pOH = 3.13
pH = 14-3.13 = 10.87
Step 3: After adding 10 mL of HCl
The reaction:
NH3 + HCl ⇔ NH4+ + Cl-
NH3 + H3O+ ⇔ NH4+ + H2O
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.010 L = 0.00025 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.00025 =0.00065 moles
Moles HCl = 0
Moles NH4+ = 0.00025 moles
Concentration at the equilibrium:
[NH3]= 0.00065 moles / 0.040 L = 0.01625M
[NH4+] = 0.00625 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.00625/0.01625)
pOH = 4.34
pH = 9.66
Step 3: Adding 20 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.020 L = 0.00050 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.00050 =0.00040 moles
Moles HCl = 0
Moles NH4+ = 0.00050 moles
Concentration at the equilibrium:
[NH3]= 0.00040 moles / 0.050 L = 0.008M
[NH4+] = 0.01 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.01/0.008)
pOH = 4.85
pH = 14 - 4.85 = 9.15
Step 4: Adding 35 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.035 L = 0.000875 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.000875 =0.000025 moles
Moles HCl = 0
Moles NH4+ = 0.000875 moles
Concentration at the equilibrium:
[NH3]= 0.000025 moles / 0.065 L = 3.85*10^-4M
[NH4+] = 0.000875 M / 0.065 L = 0.0135 M
pOH = pKb + log [NH4+]/[NH3]
pOH = 4.75 + log (0.0135/3.85*10^-4)
pOH = 6.29
pH = 14 - 6.29 = 7.71
Step 5: adding 36 mL HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.036 L = 0.0009 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.0009 =0 moles
Moles HCl = 0
Moles NH4+ = 0.0009 moles
[NH4+] = 0.0009 moles / 0.066 L = 0.0136 M
Kw = Ka * Kb
Ka = 10^-14 / 1.8*10^-5
Ka = 5.6 * 10^-10
Ka = [NH3][H3O+] / [NH4+]
Ka =5.6 * 10^-10 = x² / 0.0136
x = 2.76 * 10^-6 = [H3O+]
pH = -log(2.76 * 10^-6)
pH = 5.56
Step 6: Adding 37 mL of HCl
Calculate numbers of moles:
Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles
Moles HCl = 0.025 M * 0.037 L = 0.000925 moles
Moles NH4+ = 0 moles
Number of moles at the equilibrium:
Moles NH3 = 0.0009 -0.000925 =0 moles
Moles HCl = 0.000025 moles
Concentration of HCl = 0.000025 moles / 0.067 L = 3.73 * 10^-4 M
pH = -log 3.73*10^-4= 3.43
The pH of the solution in the titration of 30 mL of 0.030 M NH₃ with 0.025 M HCl, is:
a) pH = 10.86
b) pH = 9.66
c) pH = 9.15
d) pH = 7.70
e) pH = 5.56
f) pH = 3.43
Calculating the pH a) 0 mL
Initially, the pH of the solution is given by the dissociation of NH₃ in water.
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻ (1)
The constant of the above reaction is:
[tex] Kb = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]} = 1.76\cdot 10^{-5} [/tex] (2)
At the equilibrium, we have:
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻ (3)
0.030 M - x x x
[tex] 1.76\cdot 10^{-5}*(0.030 - x) - x^{2} = 0 [/tex]
After solving for x and taking the positive value:
x = 7.18x10⁻⁴ = [OH⁻]
Now, we can calculate the pH of the solution as follows:
[tex] pH = 14 - pOH = 14 + log(7.18\cdot 10^{-4}) = 10.86 [/tex]
Hence, the initial pH is 10.86.
b) 10 mL
After the addition of HCl, the following reaction takes place:
NH₃ + HCl ⇄ NH₄⁺ + Cl⁻ (4)
We can calculate the pH of the solution from the equilibrium reaction (3).
[tex] 1.76\cdot 10^{-5}(Cb - x) - (Ca + x)*x = 0 [/tex] (5)
Finding the number of moles of NH₃ and NH₄⁺
The number of moles of NH₃ (nb) and NH₄⁺ (na) are given by:
[tex] n_{b} = n_{i} - n_{HCl} [/tex] (6)
[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.010 L = 6.5\cdot 10^{-4} moles [/tex]
[tex] n_{a} = n_{HCl} [/tex] (7)
[tex] n_{a} = 0.025 mol/L*0.010 L = 2.5 \cdot 10^{-4} moles [/tex]
Calculating the concentrations of NH₃ and NH₄⁺The concentrations are given by:
[tex] Cb = \frac{6.5\cdot 10^{-4} moles}{(0.030 L + 0.010 L)} = 0.0163 M [/tex] (8)
[tex] Ca = \frac{2.5 \cdot 10^{-4} mole}{(0.030 L + 0.010 L)} = 6.25 \cdot 10^{-3} M [/tex] (9)
Calculating the pHAfter entering the values of Ca and Cb into equation (5) and solving for x, we have:
[tex] 1.76\cdot 10^{-5}(0.0163 - x) - (6.25 \cdot 10^{-3} + x)*x = 0 [/tex]
x = 4.54x10⁻⁵ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(4.54\cdot 10^{-5}) = 9.66 [/tex]
Hence, the pH is 9.66.
c) 20 mLWe can find the pH of the solution from the reaction of equilibrium (3).
Calculating the concentrations of NH₃ and NH₄⁺The concentrations are (eq 8 and 9):
[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 8.0\cdot 10^{-3} M [/tex]
[tex] Ca = \frac{0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 0.01 M [/tex]
Calculating the pHAfter solving the equation (5) for x, we have:
[tex] 1.76\cdot 10^{-5}(8.0\cdot 10^{-3} - x) - (0.01 + x)*x = 0 [/tex]
x = 1.40x10⁻⁵ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(1.40\cdot 10^{-5}) = 9.15 [/tex]
So, the pH is 9.15.
d) 35 mLWe can find the pH of the solution from reaction (3).
Calculating the concentrations of NH₃ and NH₄⁺[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 3.85\cdot 10^{-4} M [/tex]
[tex] Ca = \frac{0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 0.0135 M [/tex]
Calculating the pHAfter solving the equation (5) for x, we have:
[tex] 1.76\cdot 10^{-5}(3.85\cdot 10^{-4} - x) - (0.0135 + x)*x = 0 [/tex]
x = 5.013x10⁻⁷ = [OH⁻]
Then, the pH is:
[tex] pH = 14 + log(5.013\cdot 10^{-7}) = 7.70 [/tex]
So, the pH is 7.70.
e) 36 mL Finding the number of moles of NH₃ and NH₄⁺[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.036 L = 0 [/tex]
[tex] n_{a} = 0.025 mol/L*0.036 L = 9.0 \cdot 10^{-4} moles [/tex]
Since all the NH₃ reacts with the HCl added, the pH of the solution is given by the dissociation reaction of the NH₄⁺ produced in water.
At the equilibrium, we have:
NH₄⁺ + H₂O ⇄ NH₃ + H₃O⁺
Ca - x x x
[tex] Ka = \frac{x^{2}}{Ca - x} [/tex]
[tex] Ka(Ca - x) - x^{2} = 0 [/tex] (10)
Calculating the acid constant of NH₄⁺
We can find the acid constant as follows:
[tex] Kw = Ka*Kb [/tex]
Where Kw is the constant of water = 10⁻¹⁴
[tex] Ka = \frac{1\cdot 10^{-14}}{1.76 \cdot 10^{-5}} = 5.68 \cdot 10^{-10} [/tex]
Calculating the pH
The concentration of NH₄⁺ is:
[tex] Ca = \frac{9.0 \cdot 10^{-4} moles}{(0.030 L + 0.036 L)} = 0.0136 M [/tex]
After solving the equation (10) for x, we have:
x = 2.78x10⁻⁶ = [H₃O⁺]
Then, the pH is:
[tex] pH = -log(H_{3}O^{+}) = -log(2.78\cdot 10^{-6}) = 5.56 [/tex]
Hence, the pH is 5.56.
f) 37 mLNow, the pH is given by the concentration of HCl that remain in solution after reacting with NH₃ (HCl is in excess).
Calculating the concentration of HCl
[tex] C_{HCl} = \frac{0.025 mol/L*0.037 L - 0.030 mol/L*0.030 L}{(0.030 L + 0.037 L)} = 3.73 \cdot 10^{-4} M = [H_{3}O^{+}] [/tex]
Calculating the pH
[tex] pH = -log(H_{3}O^{+}) = -log(3.73 \cdot 10^{-4}) = 3.43 [/tex]
Therefore, the pH is 3.43.
Find more about pH here:
brainly.com/question/491373
I hope it helps you!
The pKa of an acid can be determined through _____ (reduction, titration, filtration) with a strong base.
Gradually increase the volume of the base, stopping _____ (before, as, after) the equivalence point is reached.
The pKa of the acid is equal to the pH at the _____ (equivalence point, midway volume to the equivalence point, maximum volume).
Answer:
The pKa of an acid can be determined through titration with a strong base.
Gradually increase the volume of the base, stopping before the equivalence point is reached.
The pKa of the acid is equal to the pH at the midway volume to the equivalence point.
Explanation:
An acid HA dissociates in water as follows:
HA ⇄ H⁺ + A⁻ Ka
So, it produces hydrogen ions (H⁺) and a conjugate base (A⁻). The concentrations of HA, H⁺ and A⁻ at equilibrium determine the constant Ka. The pKa is calculated as:
pKa = -log Ka
The relationship between the pH of the solution and the pKa of the acid is described by the Henderson-Hasselbalch equation:
pH = pKa + log ([A⁻]/[HA])
The pKa can be experimentally determined by acid-base titration, in which a strong base is added to the acid solution. As the base is added, the acid HA is neutralized and the conjugate base A⁻ is formed. Thus, the concentration of the acid ([HA]) increases and the concentration of the conjugate base ([A⁻] decreases. The equivalence point is reached when the total amount of acid is neutralized with the added base. Before reaching the equivalence point, at the halfway point, half of the acid is neutralized and converted into the conjugate base. Thus:
[A-] = [HA] ⇒ log [A-]/[HA] = log 1 = 0 ⇒ pH = pKa
We measure the pH at that point and it is equal to the pKa of the acid.
Define mass number of an atom.