Calculating the expected pH of the buffer solution: Given that the pKa for Acetic Acid is 4.77, calculate the expected pH of the buffer solutions using the Henderson-Hasselbalch equation and the concentrations of Acetic Acid and Acetate added to the 250 ml Erlenmeyer flask: pH

Answers

Answer 1

Answer:

[tex]pH=4.77[/tex]

Explanation:

From the question we are told that:

pKa for Acetic Acid [tex]pK_a= 4.77[/tex]

Therefore

For Equal Concentration of acetic acid and acetatic ion

[tex]CH_3COOH=CH_3COO^-[/tex]

Generally the Henderson's equation for pH value is mathematically given by

[tex]pH=pK_a+log\frac{base}{acid}[/tex]

[tex]pH=4.77+log\frac{CH_3COO^-}{CH_3COOH}[/tex]

[tex]pH=4.77+log1[/tex]

[tex]pH=4.77[/tex]


Related Questions

Identify each of the following properties as more typical of organic or inorganic compound
a. contains Li and F
b. is a gas at room temperature
c. contains covalent bonds
d. produces ion in water

Answers

this is the difference between organic and inorganic if this doesn't help you can research more on it

The numerical value of 0.001 is written with the prefix:

Answers

Answer:

Milli, m.

Explanation:

Hey there!

In this case, according to the given information, it turns out possible for us to answer to this question by bearing to mind the attached file whereas the most common prefixes and their factors are shown both in standard and scientific notation.

In such a way, we will be able to infer that the prefix related to the numerical value of 0.001 is milli, m, for example 1 mm which is 0.001 m.

Regards!

How much energy is released when 31.0 g of water freezes? The heat of fusion for water is 6.02 kJ/mol.
Express your answer in kilojoules to three significant figures.

Answers

Answer:

The molar heat of fusion for a given substance basically tells you how much heat is required to melt one mole of that substance at its melting point from two angles.

Explanation:

:)

What is the mass of a piece of iron if its density is 1.98 g/mL and its volume is 2.45 mL?
0.80 g
4.858
1.248
5.998
2.71 g

Answers

Answer:

4.858 g

Explanation:

Start with the formula

density = [tex]\frac{mass}{volume}[/tex]

density = 1.98 g/mL

volume = 2.45 mL

mass = ??

rearrange the formula to solve for mass

(density) x (volume) = mass

Add in the substitutes and solve for mass

1.98 g/mL x 2.45 mL = 4.858 g

For each of the scenarios, determine if the ionic strength of the solution would increase, decrease, or not change.

a. If a solution of HNO3 were added to a solution of KOH , the ionic strength of the KOH solution would:_________

1. Increase
2. Decrease
3. Not change

b. If a dilute solution of KOH were added to a solution of CaCl2 (Ca(OH)2 (s) is formed), the ionic strength would:
1. Increase
2. Decrease
3. Not change

Answers

Answer:

Increase

Decrease

Explanation:While in solution, ionic substances produce ions. The ions in solution determine the conductivity of the solution.

The ionic strength of a solution shows the concentration of ions in a given solution. The more the number of ions in the solution, the greater the ionic strength of the solution and vice versa.

When HNO3 is added to a solution of KOH, the number of ions in the solution increases and so does the ionic strength of the solution.

When KOH is added to a solution of CaCl2 then Ca(OH)2 is formed. The formation of a solid precipitate decreases the concentration of ions in solution as well as the ionic strength of the solution.

Please help thank you

Answers

Answer:

[tex]K=1.7x10^{-3}[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to solve this problem by firstly setting up the equilibrium expression for the given reaction, in agreement to the law of mass action:

[tex]K=\frac{[NO]^2}{[N_2][O_2]}[/tex]

Next, we plug in the given concentrations on the data table to obtain:

[tex]K=\frac{(0.034)^2}{(0.69)(0.98)}\\\\K=1.7x10^{-3}[/tex]

Regards!

Write the net ionic equation for the reaction that occurs when equal volumes of 0.546 M aqueous acetylsalicylic acid (aspirin) and sodium acetate are mixed. It is not necessary to include states such as (aq) or (s).

Answers

Answer:

[tex]C_9H_8O_4+C_2H_3O_2^-\rightarrow C_2H_4O_2+C_9H_7O_4^-[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to figure out the required net ionic equation by firstly writing out the complete molecular equation between aspirin and sodium acetate:

[tex]C_9H_8O_4+NaC_2H_3O_2\rightarrow C_2H_4O_2+NaC_9H_7O_4[/tex]

Whereas acetic acid and sodium acetylsalicylate are formed. Now, we write the complete ionic equation whereby sodium acetate and sodium acetylsalicylate are ionized because they are salts yet neither aspirin nor acetic acid are ionized as they are weak acids:

[tex]C_9H_8O_4+Na^++C_2H_3O_2^-\rightarrow C_2H_4O_2+Na^++C_9H_7O_4^-[/tex]

Finally, for the net ionic equation we cancel out the sodium spectator ions to obtain:

[tex]C_9H_8O_4+C_2H_3O_2^-\rightarrow C_2H_4O_2+C_9H_7O_4^-[/tex]

Regards!

What is the volume of 1.5 moles of gas at STP ?
0 9.02 L
0 20.0 L
0 33.6 L
0 22.4L

Answers

The volume of 1.5 moles of gas at STP  is 33.6 L.

Volume of the gas at STP

The volume of the gas at STP is calculated as follows;

I mole of gas at STP = 22.4 L

1.5 moles of the gas at STP = ?

= 1.5 moles  x 22.4 L/mole

= 33.6 L

Thus, the volume of 1.5 moles of gas at STP  is 33.6 L.

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Complete the table by assigning variable or fixed to the shape and volume of solids, liquids, and gases.
You are currently in a labeling module. Turn off browse mode or quick nav, Tab to items, Space or Enter to pick up, Tab to move, Space or Enter to drop.
Shape Volume
solids
liquids
gases

Answer Bank
Fixed or variable

Answers

The properties of solids, liquids and gases regarding their shapes and volumes are:

                       Shape             Volume

Solids              Fixed                Fixed

Liquids           Variable            Fixed

Gases             Variable           Variable

Solids have strong attraction forces between their molecules. Thus, the molecules are closely packed with little movement. As a consequence, both shape and volume are fixed.

In liquids, attraction and repulsion forces are similar. They have a little more movement than the solid state. Then, they do have a fixed volume but they adopt the shape of the container.

Gases have very weak attraction forces between their molecules. They move very freely and expand trying to occupy as much volume as possible. So, they have a variable volume and shape (adopt the shape of the container).

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A dehydration reaction starting with 3.0 g cyclohexanol produces 1.9 g cyclohexene. Calculate the theoretical yield for this reaction. Report your answer with two significant figures.

Answers

Answer:

77%

Explanation:

First we convert 3.0 g of cyclohexanol (C₆H₁₂O) to moles, using its molar mass:

Molar mass of C₆H₁₂O = 100.158 g/mol3.0 g ÷ 100.158 g/mol = 0.030 mol

Then we convert 1.9 g of cyclohexene (C₆H₁₀) to moles, using its molar mass:

Molar mass of C₆H₁₀ = 82.143 g/mol1.9 g ÷ 82.143 g/mol = 0.023 mol

Finally we calculate the theoretical yield:

0.023 mol / 0.030 mol * 100% = 77%

What is the relationship (formula) and proportionality
between frequency, and wavelength?

Answers

Answer:

Frequency and wavelength are inversely proportional. c=f⋅λ (The speed of light is directly proportional to f and λ)

What type of energy does a skier stopped at the top of a hill have because of
his or her position?
A. Kinetic energy
B. Gravitational potential energy
C. Heat energy
D. Chemical energy

Answers

Answer:

B

Explanation:

What is the molality of a glucose solution prepared by dissolving 16.7 g of glucose, C6H12O6, in 133.6 g of water

Answers

Answer:

0.696 m

Explanation:

We'll begin by calculating the number of mole in 16.7 g of C₆H₁₂O₆. This can be obtained as follow:

Mass of C₆H₁₂O₆ = 16.7 g

Molar mass of C₆H₁₂O₆ = (6×12) + (12×1) + (6×16)

= 72 + 12 + 96

= 180 g/mol

Mole of C₆H₁₂O₆ =?

Mole = mass / molar mass

Mole of C₆H₁₂O₆ = 16.7 / 180

Mole of C₆H₁₂O₆ = 0.093 mole

Next, we shall convert 133.6 g of water to Kg. This can be obtained as follow:

1000 g = 1 Kg

Therefore,

133.6 g = 133.6 g × 1 Kg / 1000 g

133.6 g = 0.1336 Kg

Thus, 133.6 g is equivalent to 0.1336 Kg.

Finally, we shall determine the molality of the solution. This can be obtained as illustrated below:

Mole of C₆H₁₂O₆ = 0.093 mole

Mass of water = 0.1336 Kg

Molality =?

Molality = mole / mass of water (in Kg)

Molality = 0.093 / 0.1336

Molality = 0.696 m

Therefore, the molality of the solution is 0.696 m

Jane performed the following trials in an experiment.

Trial 1: Heat 80.0 grams of water at 15.0 °C to a final temperature of 65.0 °C.
Trial 2: Heat 80.0 grams of water at 10.0 °C to a final temperature of 65.0 °C.

Which statement is true about the experiments?

The same amount of heat is absorbed in both the experiments because the mass is same.
The same amount of heat is absorbed in both the experiments because the final temperature is same.
The heat absorbed in Trial 2 is about 1,240 J greater than the heat absorbed in Trial 1.
The heat absorbed in Trial 2 is about 1,674 J greater than the heat absorbed in Trial 1.

Answers

Answer:

The heat absorbed in Trial 2 is about 1,240 J greater than the heat absorbed in Trial 1.

The heat absorbed in Trial 2 is about 1,674 J greater than the heat absorbed in Trial 1.

The amount of heat absorbed or released by a substance can be calculated using the formula Q = mcΔT, where Q represents heat, m is the mass, c is the specific heat capacity, and ΔT is the change in temperature.

In this case, the mass (m) is the same in both trials, but the initial and final temperatures (ΔT) differ. By comparing the values of ΔT in both trials, we can determine the difference in the amount of heat absorbed.

In Trial 1, the initial temperature is 15.0 °C and the final temperature is 65.0 °C, resulting in a ΔT of 65.0 - 15.0 = 50.0 °C.

In Trial 2, the initial temperature is 10.0 °C and the final temperature is 65.0 °C, resulting in a ΔT of 65.0 - 10.0 = 55.0 °C.

Since the specific heat capacity of water is approximately 4.18 J/g°C, we can calculate the difference in heat absorbed:

ΔQ = mcΔT = (80.0 g)(4.18 J/g°C)(55.0 °C - 50.0 °C) = 1,674 J

Therefore, the heat absorbed in Trial 2 is approximately 1,674 J greater than the heat absorbed in Trial 1.

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If 13.50 mL of an aluminum chloride solution is needed to reach the equivalence point with 10.00 mL of 0.109 M silver nitrate solution, determine the molarity of the aluminum chloride solution.

Answers

Answer:

If 13.50 mL of an aluminum chloride solution is needed to reach the equivalence point with 10.00 mL of 0.109 M silver nitrate solution, determine the molarity of the aluminum chloride solution.

Explanation:

The balanced chemical equation of the reaction is:

[tex]AlCl_3(aq)+3AgNO_3(aq)->3AgCl(s)+Al(NO_3)_3(aq)[/tex]

So, one mole of aluminum chloride reacts with three moles of silver nitrate.

At the equivalence point,

the number of moles of each reactant must be equal.

The number of moles = molarity x volume in L.

Number of moles of AlCl3 = volume x molarity

=0.0135Lx Molarity

The number of moles of AgNO3 = 3 x 0.010Lx 0.109M

Thus,

0.0135Lx Molarity = 3 x 0.010Lx 0.109M

Molarity of AlCl3 :

[tex]Molarity of Alcl_3=3 x 0.010Lx 0.109M/0.0135\\=0.242M[/tex]

Answer is : 0.242M.

How do I balance this equation? ?KClO3 → ?KCl + ?O2(g) and what type of reaction is it?

Answers

Explanation:

the reaction is a decomposition reaction since potassium hypochlorite is decomposed into potassium chloride and oxygen

Gold’s natural state has a definite shape and a definite volume. What is gold’s natural state

Answers

If Gold's natural state has a definite shape and a definite volume, then its natural state is solid.

Compound X has a molar mass of 266.64 g/mol and the following composition: aluminum 20.24% chlorine 79.76% Write the molecular formula of X​

Answers

Answer:

Explanation:

Assume we have 100g of this substance. That means we would have 20.24g of Cl and 79.76g of Al. Now we can find how many moles of each we have:

[tex]\frac{79.76 \:g}{35.45 \: g/mol}[/tex] = 2.25 mol of chlorine

[tex]\frac{20.24 \: g}{26.98 \: g/mol}[/tex] = 0.750 mol of Al.

To form a integer ratio, do 2.25/0.75 = 2.99999 ~= 3.

So the ratio is essentially Al : Cl => 1 : 3. To the compound is possibly [tex]AlCl_3[/tex].

However, it says it has a molar mass of 266.64 g/mol, and since AlCl3 has a molar mass of 133.32, it must be [tex]Al_2Cl_6[/tex].

Actually this molecule isn't exactly AlCl3 (which is ionic). Al2Cl6 forms a banana bond where Cl acts as a hapto-2 ligand. But that's a bit advanced. All you need to know is X = Al2Cl6

The molecular formula of the compound is Al₂Cl₆

To solve the question given above, we'll begin by obtaining the empirical formula of the compound. This can be obtained as follow:

Aluminum (Al) = 20.24%

Chlorine (Cl) = 79.76%

Empirical formula =?

Al = 20.24%

Cl = 79.76%

Divide by their molar mass

Al = 20.24 / 27 = 0.75

Cl = 79.76 / 35.5 = 2.25

Divide by the smallest

Al = 0.75 / 0.75 = 1

Cl = 2.25 / 0.75 = 3

Thus, the empirical formula of the compound is AlCl₃

Finally, we shall determine the the molecular formula of the compound.

Molar mass of compound = 266.64 g/mol

Empirical formula = AlCl₃

Molecular formula =?

Molecular formula = [AlCl₃]ₙ = molar mass of compound

[AlCl₃]ₙ = 266.64

[27 + (3×35.5)]n = 266.64

[27 + 106.5]n = 266.64

133.5n = 266.64

Divide both side by 133.5

n = 266.64 / 133.5

n = 2

Molecular formula = [AlCl₃]ₙ

Molecular formula = [AlCl₃]₂

Molecular formula = Al₂Cl₆

Therefore, the molecular formula of the compound is Al₂Cl₆

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Melanie has completed the analysis of her data for the reaction of KMnO4 with malonic acid and data for a reaction of KMnO4 with tartaric acid. She compared the activation energies, Ea, she calculated for the two reactions and found the Ea for the malonic acid reaction to be greater than the Ea for the tartaric acid reaction.

Required:
What does this mean about the magnitude of the rate constant, k, and the rate of the reaction?

Answers

Answer:

See explanation

Explanation:

The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation;

k= Ae^-Ea/RT

Where;

k= rate constant

A= pre-exponential factor

Ea=activation energy

R= gas constant

T= temperature

We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have a very high activation energy are markedly slow.

Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.

The study of chemistry and bonds is called chemistry. There are two types of elements metal and nonmetals.

The correct answer is mentioned below.

What is the Arrhenius equation?The relationship between the activation energy and rate of reaction is best captured by the Arrhenius equation

The equation is as follows:-

[tex]k= Ae^{-Ea/RT[/tex] Where;

k= rate constantA= pre-exponential factorEa=activation energyR= gas constantT= temperature

We can see from the foregoing that, as the activation energy increases, the rate of reaction decreases and vice versa. reactions that have very high activation energy are markedly slow. Since the activation energy for the malonic acid reaction is found to be greater than the activation energy for the tartaric acid reaction, then the rate of the malonic acid reaction(k) will be slower than that of the tartaric acid reaction.

Hence, the correct answer is mentioned above.

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Anyone can help me out please?!

Answers

For consumption of each gram of reactant released=37.9 kJ/g

Therefore, for consumption of 4kg of reactant heat released=37.9x4 kJ/g

Balance the following skeleton reaction and identify the oxidizing and reducing agents:

CrO42- (aq) + N2O(g)+ H+(aq) + OH-(aq) + H2O(l) ⟶ Cr3+(aq) + NO(g) + H+(aq) + OH-(aq) + H2O(l)

oxidizing agent is (enter just the formula of the species, e.g. CrO42-,N2O, Cr3+,NO, H2O, H+, OH-)
reducing agent is (enter just the formula of the species, e.g. CrO42-,N2O, Cr3+,NO, H2O, H+, OH-)

Answers

Answer:

The balanced net ionic equation is as follows:

CrO₄²- (aq) + 3 N₂O (g) + 2 H+ (aq) ----> Cr³+ (aq) + 6 NO (g) + H₂O (l)

The oxidizing agent is CrO₄²- as Cr⁶+ in CrO₄²- is reduced to Cr³+.

The reducing agent is N₂O as the nitrogen (i) is oxidized to nitrogen (ii).

Explanation:

The skeleton equation is given as follows:

CrO₄²- (aq) + N₂O(g)+ H+(aq) + OH-(aq) + H2O(l) ----> Cr³+(aq) + NO(g) + H+(aq) + OH-(aq) + H₂O(l)

The balanced net ionic equation with the spectator ions removed is as follows:

CrO₄²- (aq) + 3 N₂O (g) + 2 H+ (aq) ----> Cr³+ (aq) + 6 NO (g) + H₂O (l)

In a redox reaction, oxidizing agents are reduced while reducing agents are oxidized.

The oxidizing agent is CrO₄²- as Cr⁶+ in CrO₄²- is reduced to Cr³+.

One mole of CrO₄²- accepts three moles of electrons from three moles of N₂O to become reduced to 1 mole of Cr³+.

The reducing agent is N₂O as the nitrogen (i) is oxidized to nitrogen (ii).

Three moles of N₂O will each donate one mole of electrons to one mole of CrO₄²- to become oxidized to nitrogen (ii) oxide.

Hydrogen ions and a water molecule is added to the left-hand side and right-hand side of the equation respectively, in order to balance the number of oxygen atoms in the equation of the reaction.

A major component of gasoline is octane (C8H8). When liquid octane is burned in air it reacts with oxygen (O2) gas to produce "0.050 mol" carbon dioxide gas and water vapor. Calculate the moles of octane needed to produce of carbon dioxide.

Answers

Answer:

0.0063 mol

Explanation:

Step 1: Write the balanced combustion equation

C₈H₁₈(l) + 12.5 O₂(g) ⇒ 8 CO₂(g) + 9 H₂O(g)

Step 2: Establish the appropriate molar ratio

According to the balanced equation, the molar ratio of C₈H₁₈ to CO₂ is 1:8.

Step 3: Calculate the number of moles of C₈H₁₈ needed to produce 0.050 moles of CO₂

0.050 mol CO₂ × 1 mol C₈H₁₈/8 mol CO₂ = 0.0063 mol C₈H₁₈

The Tollen's test is the reaction of aldehydes with silver(l) ions in basic solution to form silver metal and a carboxylate. 2 Ag+ + + 3 OH- - HR 2 Ag +_ W + 2 H2O ÃR Which species is being oxidized in the reaction? Choose... Which species is being reduced in the reaction? Choose... Which species is the visual indicator of a positive test? v Choose... Carboxylate ion Aldehyde Silver metal Water Silver(1) ion Hydroxide ion

Answers

Answer:

Explanation:

When Tollen's test is done by aldehyde , silver ion is converted into silver which forms a layer which looks like a mirror.

Ag⁺ + e = Ag

It is a reduction process where silver(1) ion is reduced to metallic silver.

Aldehyde is oxidized to carboxylate ion.

CH₃CHO + 2 OH⁻ = CH₃COO⁻ + H₂O + H⁺ + 2e

Visual indicator is silver metal which forms silver mirror at the bottom of test tube .

Stalactites and stalagmites form as ________ precipitates out of the water evaporating in underground caves.

Answers

Stalactites and stalagmites form as ________ precipitates out of the water evaporating in underground caves.

Group of answer choices

hydrochloric acid

sodium bicarbonate

calcium carbonate

sodium chloride

sodium hydroxide

Answer:

calcium carbonate

Explanation:

A stalactite is an icicle-looking mould that is formed by the precipitation of natural minerals as a result of water dripping from the ceiling, hanging from a cave.

A stalagmites in the other hand, grows upwards and is also a mound that is formed by the deposits of minerals gotten by the water dripping on the floor of a cave.

Therefore, stalactites and stalagmites form as calcium carbonate precipitates out of the water evaporating in underground caves.

Which of the following would tell you that a weak base is present?
A. If the pH of the solution is close to 14.
B. If the solution is a good conductor of electricity.
C. An indicator added to the solution turns green-blue.
D. If there is a high reaction rate.

Answers

Answer:

An indicator added to the solution turns green-blue.

Explanation:

An indicator is a substance which shows the degree of acidity or alkalinity of a solution by change in colour of the solution.

The universal indicator changes colour as the pH of the solution changes. Looking at the colour ranges for the universal indicator, the green-blue colour indicates a weak base.

Proteins are:
amino acids.
carbohydrates.
minerals.
sugars.

Answers

Proteins are Amino acids
Proteins are made of amino acids. They are macromoluces made up of smaller amino acid chains.

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Determine whether each of the following statements is true or false. If false, correct the statement to make it true: (a) The nucleus has most of the mass and comprises most of the volume of an atom. (b) Every atom of a given element has the same number of protons. (c) The number of electrons in an atom equals the number of neutrons in the atom. (d) The protons in the nucleus of the helium atom are held together by a force called the strong nuclear force.

Answers

Answer:

Every atom of a given element has the same number of protons

The protons in the nucleus of the helium atom are held together by a force called the strong nuclear force.

Explanation:

Atoms are composed of electrons, protons and neutrons. The electron is negatively charged, protons are positively charged and the neutrons have no charge.

Electrons are found in shells while protons are found inside the atomic nucleus. Similar to electrostatic forces between electron and proton, protons of helium are held together by a strong nuclear blinding force.

Note that, all isotopes must have the same atomic number. This shows that they are all the same atom changed by differences in number of neutrons.

A calorimeter measures the Choose... involved in reactions or other processes by measuring the Choose... of the materials Choose... the process. The calorimeter is Choose... to prevent transfer of heat to outside the device.

Answers

Answer:

heat; temperature; surrounding; insulated.

Explanation:

A calorimeter can be defined as a scientific instrument (device) that is designed and developed for measurement of the heat involved in chemical reactions or other processes, especially by taking the measurement of the temperature of the materials surrounding the process.

Basically, a calorimeter is insulated using materials with a very high level of resistivity, so as to prevent heat transfer to the outside of the device (calorimeter).

Some of the components that make up a simple calorimeter are; thermometer, an interior styrofoam cup, an exterior styrofoam cup, cover, etc.

Additionally, a calorie refers to the amount of heat required to raise the temperature of a gram of water by one degree Celsius (°C)

A calorimeter measures the heat involved in reactions or other processes by measuring the temperature of the materials surrounding the process. The calorimeter is insulated to prevent transfer of heat to outside the device.

What is calorimeter?

Calorimeter is an instrument used in chemical reactions for measuring the heat, physical changes as well as heat capacity of the chemical reaction.

From the definition of calorimeter it is clear that it checks the temperature of the reaction and calculates the heat of the chemical reaction. It is insulated by those materials which are bad conductors of heat so that no heat will loss from this apparatus.

Hence, correct options are heat, temperature, surroundings and insulated.

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Kati was in the kitchen when she heard a crash. She went into her bedroom and found her window broken and a baseball lying on the ground. Kati said "this baseball broke my window." This statement is an

Answers

Answer:  inference because she drew a conclusion based on evidence.

why?:

Because the evidence was that she heard the crashing sound, and then when she came into her room saw the broken window and baseball.

It was not an observation because she did not directly see the baseball going through the window

the answer is inference

Kingsley then adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution. The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO left in solution. Determine the pH of the resulting solution. Which of the following acids would produce the highest pH at the equivalence point in a weak acid-strong base titration?
Ka(HF) =6.8x10-4
Ka(HNO2) =4.5x10-4
Ka(HCIO2) =1.1x10-2
K(CH3COOH) =1.8x10-5
i. HCIO2
ii. CH3COOH
iii. HF
iv. HNO2

Answers

Answer:

i. HCIO2 - 2.9

ii. CH3COOH - 2.64

iii. HF - 3.27

iv. HNO2 - 2.67

Explanation:

The Ph value differ for base and acid. A neutral solution will have Ph value of 7. For acid the Ph value is less than 7 and for base Ph value is greater than 7. The highest Ph value for the given acids is 3.27 for hydroflouric acids.

The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

The neutralization reaction resulted in 0.098 moles of HCOOH and 0.025 moles of HCOO⁻ left in the solution.

We have to determine the pH of the resulting solution and identify the acid that would produce the highest pH at the equivalence point in a weak acid-strong base titration.

What is pH?

pH, a quantitative measure of the acidity or basicity of aqueous or other liquid solutions.

Kingsley adds 49.28 mL of NaOH to 250.00 mL of the HCOOH solution.

Total volume of the solution = 49.28 mL + 250.0 mL = 299.28 mL = 0.29928 L

At neutralization point, HCOOH = 0.098 mol = [tex]\frac{0.098\ mol}{0.29928\ L} = 0.32745\ M[/tex]

So, Concentration of HCOOH at neutralization point = 0.32745 M

And [tex]HCOO^-[/tex] at neutralization point = 0.025 mol = [tex]\frac{0.025\ mol}{0.29928\ L} = 0.08353\ M[/tex]

So, Concentration of HCOO⁻ at neutralization point = 0.08353 M

Now, [tex]K_a[/tex] value of HCOOH = [tex]1.77\times10^{-4}[/tex] (reference value}

We know that [tex]pK_a = -logK_a[/tex]

[tex]pK_a = -log(1.77\times10^{-4}) = 3.75[/tex]

Now, HCOOH  is acid and HCOO⁻ is the conjugate base.

According to Henderson Hasselblach equation:

[tex]pH = pK_a + log\frac{[conjugate\ base]}{[acid]}\\ \therefore pH = 3.75 + log\frac{[HCOO^-]}{[HCOOH]}\\pH = 3.75 + log(\frac{0.08353}{0.32745})\\pH = 3.75 +(-0.59)\\pH = 3.16[/tex]

Therefore, the pH of the resulting solution is 3.16.

When weak acid is titrated with a strong base, the pH at the neutralization point is always greater than 7. It is because the conjugate base produced by weak acid in neutralization reaction is comparatively stronger in nature which produces [tex]OH^-[/tex] at neutralization point after reacting with water. so the solution is basic. As a result, pH is more than 7.

Now, the weaker is the acid, the stronger is the conjugate base, and vice-versa. Therefore, the concentration of [tex]OH^-[/tex] ions is more at the neutralization point. So more will be the pH value.

Given acids with the corresponding [tex]K_a[/tex] value are shown below:

[tex]K_a(HF) =6.8\times10^{-4}\\K_a(HNO_2) =4.5\times10^{-4}\\K_a(HClO_2) =1.1\times10^{-2}\\K_a(CH_3COOH) =1.8\times10^{-5}[/tex]

We know that lower the value of [tex]K_a[/tex] of  acid, the weaker is the acid and vice-versa. Hence, [tex]CH_3COOH[/tex] has lowest [tex]K_a[/tex] value compared to other acids. Therefore, [tex]CH_3COOH[/tex]  would  produce the highest pH at the equivalence point in a weak acid-strong base titration.

Hence, The pH of the resulting solution is 3.16. Acetic acid having the formula [tex]CH_3COOH[/tex] would produce the highest pH at the equivalence point in a weak acid-strong base titration.

To learn more about, acid-base titrations, click here:

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